You can selectively color just of one person in a group or an individual item. Here's how!
Open an image. It is good if this is colored. We will use this image of 3 young ladies.
Select the Freehand Lasso Tool set at Point to Point.
Draw around which ever girl you want to be selectively colored.
Copy the selection to your clipboard.
Deselect the image. Selection || Select None.
Go to Colors || Greyscale and turn the image into a black and white photo.
Now back to Colors and Increase Color Depth to 16 Million Colors.
Go Edit || Paste as New Layer.
Move the selected girl over the top of the original.
Merge your layers and save as.
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